N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoroacetyl)-N,N′-dimethylphosphoric triamide
نویسندگان
چکیده
منابع مشابه
N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoroacetyl)phosphoric triamide
In the title mol-ecule, C(16)H(17)ClF(2)N(3)O(2)P, the N-H unit of the C(=O)NHP(=O) fragment adopts a syn orientation with respect to the P=O group. The two F atoms and the Cl atom of the ClF(2)C group are disordered over two sets of sites with refined occupancies of 0.605 (6) and 0.395 (6). In the crystal, mol-ecules are linked via N-H⋯O=C hydrogen bonds the and the (N-H⋯)(N-H⋯)O=P group into ...
متن کاملN,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoroacetyl)-N,N′-dimethylphosphoric triamide
In the title mol-ecule, C(18)H(21)ClF(2)N(3)O(2)P, the P=O and N-H groups are syn to each other. The P atom adopts a slightly distorted tetra-hedral environment and the N atoms of the tertiary amine groups are bonded in an essentially planar geometry. In the crystal, pairs of inter-molecular N-H⋯O(P) hydrogen bonds form centrosymmetric dimers.
متن کاملN,N′-Dibenzyl-N′′-(2-chloroacetyl)-N,N′-dimethylphosphoric triamide
In the title mol-ecule, C(18)H(23)ClN(3)O(2)P, the P atom is bonded in a distorted tetra-hedral environment. The P=O and N-H groups are syn with respect to each other. The angles at the tertiary N atoms confirm their sp(2) character. In the crystal, pairs of inter-molecular P=O⋯H-N hydrogen bonds form centrosymmetric dimers.
متن کاملN,N′-Dibenzyl-N′′-(4-bromobenzoyl)-N,N′-dimethylphosphoric triamide
In the title compound, C(23)H(25)BrN(3)O(2)P, the P atom has a distorted tetra-hedral coordination. In the crystal structure, the mol-ecules form centrosymmetric dimers via pairs of essentially linear N-H⋯O hydrogen bonds.
متن کاملN,N′-Dibenzyl-N′′-(2,4-difluorobenzoyl)-N,N′-dimethylphosphoric triamide
In the title mol-ecule, C(23)H(24)F(2)N(3)O(2)P, the P atom is in a distorted tetra-hedral P(=O)(N)(N)(2) environment, with the bond angles around the P atom in the range 106.78 (11)-114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relative to each other. In the C(=O)NHP(=O) fragment, the P-N bond is longer [1.683 (2) Å] and the O-P-N...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811005423